Abstract
Bis(diisopropylammonium) sulfate, 2C6H16N+·SO42−, crystallizes in the monoclinic centrosymmetric space group P21/n. The asymmetric unit contains two crystallographically independent diisopropylammonium cations and one sulfate anion in general positions. Strong hydrogen bonding occurs between the cations and anions, forming layers parallel to (\overline 101). Each layer is composed of ring systems that can be classified according to Etter's nomenclature as R44(12) and R1212(36). IR and Raman spectroscopy confirm the presence of a nearly undistorted sulfate anion.
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