Abstract

In the title compound, 2C14H14NO+·I3−·I−, the cations are almost planar and exist in E configurations. The dihedral angles between the pyridinium and benzene rings in the two unique cations are 2.6 (2) and 2.8 (2)°. O—H⋯I hydrogen bonds and weak C—H⋯I inter­actions are observed in the crystal structure. The cations are arranged in a zigzag fashion along the c axis and are packed in an anti­parallel manner into sheets parallel to the bc plane. These sheets are inter­connected via O—H⋯I hydrogen bonds and weak C—H⋯I inter­actions to form a three-dimensional network.

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