Abstract
AbstractHerein, a series of molecular nickel tripyridine‐diamine catalysts endowed with different proximal functional groups −NH2 (1), −CH3 (2), and −OCH3 (3) in the second coordination sphere for hydrogen evolution from neutral water are reported. The −NH2 group shows a beneficial effect in the hydrogen evolution reaction. Intramolecular protonation on reductive nickel core assisted by the positioned amine in complex 1 results in a much faster protonation rate than that of 2 and 3, and is responsible for the higher catalytic activity in neutral water.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
