Abstract
AbstractDiblock copolymerizations of L‐ or D,L‐lactide (LA) with trimethylene carbonate (TMC) or 2,2‐dimethyltrimethylene carbonate (2,2‐DTMC) with SmMe(C5Me5)2‐(tetrahydrofuran) as an initiator and triblock copolymerizations of L‐ or D,L‐LA/cyclic carbonates/L‐ or D,L‐LA with [Sm(C5Me5)2]2(PhCCCCPh) as an initiator generated the desired block copolymers. This article describes the comparison of biodegradabilities by proteinase K and a compost and mechanical properties between the resulting di‐ or triblock copolymers and random copolymers composed of L‐ or D,L‐LA and cyclic carbonates. The scanning electron microscopic profiles of resulting polymers were measured to understand the morphological change during biodegradation. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3572–3588, 2003
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More From: Journal of Polymer Science Part A: Polymer Chemistry
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