Abstract
The efficient cleavage of plasmid DNA (pCAT) by binuclear lanthanide complexes was investigated. At 37°C and neutral pH, both Ho 2 3+L and Er 2 3+L promoted 100% conversion of supercoiled plasmid to the nicked circular form and linear form in 1 h. The corresponding saturation kinetics curve of cleavage of pCAT plasmid by binuclear lanthanide complexes showed the expected increase with catalyst concentration.
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