Abstract
The reaction mechanisms with Li of various metal oxides, sulfides and a selenide in nonaqueous electrolyte have been studied by the galvanostatic method, X-ray diffraction analysis, and ion-microanalysis. As a result, cell reactions were classified into 3 types. (1) The directly reduced type: cathode materials are reduced directly to metal; CuO, etc. (2) The 2 step reaction type: reaction proceeds through intermediate products: FeS 2 (3) The solid diffusion type, based on the so-called intercalation reaction; MnO 2, TiS 2, etc.
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