Abstract
Three new barium bismuth oxides have been synthesized containing 2.15–2.72 mol % BaO with the integer composition BaBi39O59.5, BaBi46O70, and BaBi40O61 and a monoclinic, cubic, and triclinic structure, respectively. These double oxides are, likely, derivatives of α-, γ-, and ɛ-Bi2O3 phases. The effects of the crucible material and surrounding atmosphere on the course of the synthesis of these new barium bismuth oxides are elucidated.
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