Abstract
Background: This review focuses on the recent advances in the asymmetric hydrogenation of pro-chiral C=O and C=N double bonds catalyzed by iron-catalysts based on chiral and achiral Knölker type complexes. Keywords: Activated double bond, asymmetric hydrogenation, bifunctional catalyst, (cyclopentadienone)iron–tricarbonyl complexes, iron, Knölker's complex.
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