Abstract
Hydrogen transfer reduction of various ketones occurs in a mixture of perfluoroalkane/isopropanol using iridium complexes in association with chiral perfluorinated diimines or diamines as ligands. Enantioselectivity of up to 79% has been obtained. Recycling of the catalyst using chiral perfluorinated diamines as the ligands is possible with no loss of enantioselectivity and very low leaching of iridium in the organic phase.
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