Abstract
AbstractNickel‐catalyzed reductive coupling reactions of 1,3‐enynes and aromatic aldehydes efficiently afford conjugated dienols in excellent regioselectivity and modest enantioselectivity when conducted in the presence of catalytic amounts of a monodentate, P‐chiral ferrocenyl phosphine ligand. 1‐(Trimethylsilyl)‐substituted enynes are shown to be effective coupling partners in these reactions, and the dienol products thus formed readily undergo protiodesilylation under mild conditions.
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