Abstract
The deuterium and chlorine relaxation times of CDCl3 have been measured in solutions of diethyl ether, n-dibutyl ether, and various polyethers. The data have been analysed assuming anisotropic rotational diffusion of CDCl3 in 2 possible states, a ‘free’ state, and a ‘bound’ state where CDCl3 forms a 1:1 complex with any R–O–R′ unit. By extrapolating to the limit of dilute ether solutions, rotational correlation times are obtained for motions of the complex in the chloroform solvent.
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