Abstract
In order to identify the causes that led to microbiological degradation by biofouling increases a top coat painting layer applied to a railway bridge was analyzed by both FTIR and the DSC methods; the analysed painting material was that used to paint the bridge in 2013.The determinations were performed comparatively on samples of a similar painting material after 10 days of curing in a natural atmosphere at 25 � 5 �C, after 60 days of storage under laboratory conditions (22 � 5 �C, RH 60 � 10 %, natural lighting), and on samples from the painting material of a certain railway bridge after approx. 4.5 years (exposed natural weathering of temperate climate with Mediterranean influences). From FTIR determinations, the amount of oxygen containing groups (C = O, C-O, C-O-C, -HO) resulted from ageing under various conditions of the painting material.From DSC determinations, the resistance of the paint to the oxidative degradation decreases with the ageing time as resulted from oxidation onset temperatures and oxidation activation energies values - which decreases with 4 kJ / mole (about 2.2 %) in only 60 days of storage in the laboratory and with 7 kJ/mole (about 3.9 %) following exposure to 100 w/m2 for only 15 h and 29 kJ / mole (over 16 %) after exposure to 4.5 years of natural weathering.
Highlights
In order to identify the causes that led to microbiological degradation by biofouling increases a top coat painting layer applied to a railway bridge was analyzed by both FTIR and the DSC methods; the analysed painting material was that used to paint the bridge in 2013.The determinations were performed comparatively on samples of a similar painting material after 10 days of curing in a natural atmosphere at 25 ± 5 °C, after 60 days of storage under laboratory conditions (22 ± 5 °C, RH 60 ± 10 %, natural lighting), and on samples from the painting material of a certain railway bridge after approx. 4.5 years
In our case FTIR spectroscopy was used to characterize the ageing effects induced by the exposure of the paint in various environmental conditions by observing the optical absorptions corresponding to the presence and groth of oxidative groups or the double bonds (C=C)
The exposure of the polyurethane paint to various environmental conditions leads to some modifications in the ATR/FTIR spectrum, which are related to changes in the chemical structure of the material
Summary
In order to identify the causes that led to microbiological degradation by biofouling increases a top coat painting layer applied to a railway bridge was analyzed by both FTIR and the DSC methods; the analysed painting material was that used to paint the bridge in 2013.The determinations were performed comparatively on samples of a similar painting material after 10 days of curing in a natural atmosphere at 25 ± 5 °C, after 60 days of storage under laboratory conditions (22 ± 5 °C, RH 60 ± 10 %, natural lighting), and on samples from the painting material of a certain railway bridge after approx. 4.5 years (exposed natural weathering of temperate climate with Mediterranean influences). In our case FTIR spectroscopy was used to characterize the ageing effects induced by the exposure of the paint in various environmental conditions (artificial UV, natural weathering, darkness) by observing the optical absorptions corresponding to the presence and groth of oxidative groups (carbonyl, carboxyl and hydroxyl) or the double bonds (C=C).
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