Assessing the vulnerability of over-exploited volcanic aquifer systems using multi-parameter analysis, Toluca Basin, Mexico

Abstract

The potential for contamination of groundwater in an over-exploited system led to this investigation on aspects of aquifer vulnerability in the Toluca Basin, Mexico. This study involved the use of various hydrogeological, geochemical and isotopic tools to better understand the susceptibility to contamination where heavy groundwater extraction along with industrial extensive development is concentrated. Geochemical and isotopic analyses of groundwater from production wells along the mountain boundary show little evidence of contamination at present time. Radiocarbon and tritium data collected in piezometers and wells penetrating the Lower basalt aquifer indicate that the groundwater is of varying age and quality. These data, in addition to stable isotope and chemical data also indicate evidence of contamination in the Lower aquifer; which could be associated with fast recharge in the mountains or injection of waste water by illegal wells. Evidence found in this study of low downward gradients in the valley fill sediments and the presence of low permeability aquitard deposits suggest that the aquifer system is currently not highly threatened by surface sources of contamination. However, where urban and industrial development occurs, in the centre of the valley and along the flanks of the Basin, the vulnerability of the aquifer system increases significantly.