Abstract

From the available thermochemical data on eight oxides and silicates, complete sets of data on heat capacity, isobaric thermal expansion, isothermal compressibility and Gibbs free energy of formation have been generated by using an optimization technique. These data are made internally consistent satisfying the relationship between the heat capacity at constant pressure and constant volume, thermal expansion and bulk modulus. The data can be extrapolated to temperatures beyond melting as are needed in high pressure phase equilibrium calculations.

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