Abstract
AbstractA Pd‐catalyzed sequential C−C/C−S cleavage and C−S formation approach for highly functionalized allylic sulfones synthesis of vinylcyclopropanes with p‐tosylmethyl isocyanide has been developed under mild conditions. Importantly, the reaction of modular VCPs and TosMIC would give access to (E)‐allylic sulfones in a stereoselective and regioselective fashion onto the in situ formed Pd intermediate. The current protocol featured broad substrate scope, operational convenience, and gram‐scale production.
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