Abstract
The substitution reactions of a NO-ligated dinuclear ruthenium complex with ammonium thiocyanate (NH4SCN), sulfur, and dimethyl sulfoxide (DMSO) gave the corresponding mononitrosyl dinuclear complexes, except for reaction with sulfur, where diastereomers of a S2-bridged tetranuclear complex along with a NO- and S2-bridged dinuclear complex were obtained. According to the scan rate dependent cyclic voltammograms, linkage isomerism of a dmso ligand on the dinuclear complex was revealed, and the linkage isomer was obtained from the chemical oxidation.
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