Abstract
Rückgrat zeigen: Das Spiroketal-Rückgrat des Diphosphan-Liganden 1 gewährleistet gute Regio- und Enantioselektivitäten in der Palladium-katalysierten asymmetrischen allylischen Aminierung von racemischen Morita-Baylis-Hillman-Addukten mit aromatischen Aminen. Die Methode bietet eine einfache und effiziente Synthese von Vorstufen für optisch aktive β-Lactame, einschließlich des Cholesterinsenkers Ezetimib.
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