Abstract
The crystal structure of the title compound, [Mn(TPP)(η1-H2Btz2)(H2O)]·H2O [where H2Btz = dihydrobis(1,2,4-triazolyl)borate, C4H6BN6, and TPP = tetraphenylporphyrin, C44H20N4], contains a singly coordinated H2Btz2. The TPP ligand is highly distorted even though the coordination environment around MnIII has regular octahedral geometry. Both coordinated and uncoordinated water molecules are involved in intermolecular hydrogen bond through O—H⋯O, O—H⋯N and O—H⋯(π-arene) interactions to form a three-dimensional network.
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