Abstract

Non-symmetrical bromoiodanes are useful for bromination reactions, and some protocols were found to be suitable for specific substrates. Herein, we report the use of a DIB/BBr3 protocol for various bromination reactions, including electrophilic bromination of arenes, carbonyl C-H monobromination, bromolactonization, bromocarbocyclization, intermolecular bromoetherification of olefin, and light-triggered C(sp3)-H bromination.

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