Abstract

According to the boundary theory of isobaric phase diagrams, the relationship among NPRs and their boundaries in unary, binary and ternary phase diagrams of all types (including isothermal and isopleth sections), could, with advantage, be systematically clarified. With the aid of boundary theory, Rhines’ ten empirical rules concerning the construction of complicated ternary phase diagrams from phase diagram units are well expounded. A comparison, made between the boundary theory and Palatnik-Landau’s contact rule of phase regions, is also presented in this chapter.

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