Applicability of coal slag for application as packed bed thermal energy storage materials

Abstract

Refractory materials are considered as the most suitable high-temperature sensible heat storage materials due to their excellent thermo-mechanical resistance and superior thermophysical properties. Unfortunately, refractories are usually too expensive. To reduce the cost of energy storage materials, the recycling of refractory industrial solid wastes into storage materials is becoming increasingly prevalent. The paper innovatively proposes to use the slags from a liquid slagging furnace of a coal-fired power plant in China as packed bed sensible heat energy storage materials. This paper characterizes the chemical compositions and thermophysical properties of three typical coal slags (Fukang coal slag, Fukang coal granulated slag, Hongshaquan coal granulated slag) and evaluates their potentials as storage materials. The results show that the three kinds of coal slags have good thermophysical properties. At 380 °C, the energy storage densities per unit volume of the three materials are 1037 MJ/m3, 986 MJ/m3 and 920 MJ/m3, respectively. Fukang coal slag has good thermal stability and durability and can be directly used for ultra-high temperature energy storage at 1000 °C. Due to the low crystallization degree, the two granulated slags have poor thermal durabilities and need to be processed at high temperatures before using them for energy storage applications.