Abstract
The title compound, rac-[Ca(C24H12)(C4H8O)2], was synthesized using activated calcium and the neutral ligand in the presence of THF. Both enantiomers are present in the asymmetric unit. The Ca atom is in a distorted pseudo-tetrahedral four-coordinate environment with the following range of bond distances and angles (Cp = cyclopentadienyl centroid): Cp—Ca 2.347 (4)–2.446 (4) Å, Ca—O 2.346 (4)–2.357 (4) Å, Cp—Ca—Cp 118.8 (2)–119.1 (2)° and O—Ca—O 87.39 (14)–87.93 (13)°.
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