Abstract

The results of high-temperature (20≤T≤800°C) relaxation and magnetic investigations of ferrite Li0.5Fe2.5O4 in various structural states are given. Anomalies of internal friction caused by the occurrence of ferrimagnetic and structural (ordering type) second-order phase transitions and by vibrations of domain walls of ferrimagnetic and antiphase domains were revealed. It is shown that the 1: 3 ordering of Fe3+ and Li+ ions in the octahedral sublattice of the spinel leads to a decrease in the Curie temperature, a change in the character of the temperature dependence of the low-field magnetization, and a narrowing of the temperature range of the structural phase transition, as well to a substantial weakening of dissipation processes connected with vibrations of ferrimagnetic domain walls in the field of elastic stresses.

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