Abstract
A series of novel complexes of the type M 2 [FeX 4L] where M +=K + or Na +; X=cyanate, thiocyanate or azide; L=pyridine- N-oxide, γ-picoline- N-oxide or L- ascorbic acid; have been synthesized by the reaction of the metal salt and ligands in the appropriate ratio in mixed solvent (water-ethanol) medium. The complexes were characterized on the basis of their analyses, molar conductance, magnetic susceptibility, infrared, electronic spectral data and molecular weight measurements. The compounds are found to be 1:2 electrolytes and penta-coordinated monomers with presumably square pyramidal geometry.
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