Abstract
Na based all-solid-state batteries are one of the most promising candidates for large-scale electrochemical energy storage owing to their low cost and outstanding safety properties. The key enabler of this technology is solid electrolyte with sufficiently high ionic conductivity at room temperature. In this work, the design, synthesis, characterization, and testing of a series of novel fast Na-ion conductors, Na4-x-ySn1-xAxS4-yXy with aliovalent cation (P5+/Sb5+) and anion (Cl−/Br−) substitutions of the parent compound Na4SnS4 are reported. The doped samples crystalize in a new phase with space group I41/acd and show ionic conductivities that are one to four orders of magnitude higher than that of undoped Na4SnS4. R. t. conductivity of 0.64 mS cm−1 is achieved in Na3.7Sn0.8Sb0.2S3.9Cl0.1 with a low activation energy of 0.26 eV. Rietveld refinement against high resolution synchrotron X-ray powder diffraction data reveals that the distribution of the doping ions and the resulted Na vacancies are underlying causes of the enhanced conductivity.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
