Abstract
In this review, the fine structure of polymers obtained by radiation-induced polymerization in the solid state, i.e., poly(tioxane) and poly(tetroxocane), is characterized by X-ray scattering, melting behavior, and radiolysis. The annealing effects on these behaviors gave quite valuable information to clarify the fine structure of the original material, since the materials used here are crystalline samples. Electron microscopic studies were also performed to confirm the suggested structure in the case of the irradiated samples.
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