Abstract
An unprecedented supramolecular network formed by [Ag(4,4′-bipyridine)]n chains and [Ag(NO3)4]3− anions via Ag⋯O interaction shows four types of channels filled by [Ag(4,4′-bipyridine)]n chains, [Ag(benzimidazole)]n chains and water molecules, representing the first example of cocrystallization of two 1D infinite coordination polymer chains.
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