Abstract

Mittendrin: Die zweikernige Eisen(III)-Enterobactin-Modellverbindung [{Fe(mecam)}2]6− (H6-mecam=1,3,5-N,N′,N′′-Tris(2,3-dihydroxybenzoyl)triaminomethylbenzol)wird von zwei Molekülen eines periplasmatischen Bindungsproteins (gelb und blau; siehe Struktur) erkannt. Das Aggregat wird durch hydrophobe Wechselwirkungen zwischen den Liganden des zweikernigen Eisenkomplexes stabilisiert.

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