Abstract
The anionic high oxidation state molybdenum (VI) amidato bisalkyl alkylidyne complex [(Mo(N-2,6-Me2-C6H3)(CH2CMe3)2(CCMe2Ph)(Mg.Et2O-μ-Cl)2], 1, is reported. It forms via reaction of Mo(N-2,6-Me2-C6H3)(CHCMe2Ph)(O3SCF3)2.DME (DME = 1,2-dimethoxyethane), with an excess of neopentylmagnesium chloride. DFT calculations suggest a mesomerization between an amidato-alkylidyne and imido alkylidenato complex.
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