Amorphous CeOx Islands on Dealuminated Zeolite Beta to Stabilize Pt Nanoparticles as Efficient and Antisintering Catalysts for Propane Dehydrogenation.

Abstract

Pt-based catalysts have been widely used in propane dehydrogenation due to their superior activation of C-H bonds and weak scission of C-C bonds. However, in the process of repeated calcination to remove deposited coke, the active Pt species tend to sinter, resulting in a significant decline in catalytic activity. In this study, amorphous CeOx islands loaded on dealuminated Beta zeolite were prepared via simple wetness impregnation. Then, partially embedded Pt nanoparticles in CeOx islands were obtained after reduction owing to the affinity of CeOx for Pt. In the propane dehydrogenation reaction, Pt/Ce5-SiBeta with a Ce loading of 4.55 wt % and Pt loading of 0.72 wt % exhibited the highest activity and the lowest inactivation constant at 550 °C. More importantly, due to the anchoring effect of CeOx on Pt, the catalytic activity of Pt could be recovered after a simple calcination-reduction regeneration process, avoiding the chlorination treatment for the redispersion of Pt species used in industry. In addition, to improve the selectivity of the Pt/Ce5-SiBeta catalyst, a PtSn/Ce5-SiBeta catalyst with excellent activity, selectivity, and recycling stability has been prepared by introducing Sn into Pt/Ce5-SiBeta. The use of amorphous CeOx islands to improve the sintering resistance of Pt opens up new prospects for the design of stable industrial dehydrogenation catalysts.