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Ammonium-based fertilizers alter pH and cation concentrations in agricultural soils of Saskatchewan, Manitoba and Quebec

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Soil pH is a key component of soil health, influencing chemical, biological and related processes such as nutrient cycling. Globally, it has been recognized for decades that fertilization with ammonium fertilizers (including ammonium nitrate, urea and ammonium phosphate) at high rates and/or over long time periods can decrease soil pH, and is of particular concern in soils with naturally neutral pH (6.5-7.0) due to reduced buffering capacity. To investigate acidification in Canadian agriculture, soils were sampled from the 0-5, 5-10 and 10-20 cm depths from long-term research plots in historically neutral-pH soils in Saskatchewan (SK) and Quebec (QC), and a shorter-term N fertilization trial in SK and Manitoba (MB), under a range of fertilization practices including with and without chemical N fertilization, organic management with no fertilizers (chemical or animal manure), and a range of management practices, including tillage and crop rotations. Soil pH ranged from 5.0 to 7.3 in SK and QC soils and up to 8.4 in MB soils, and was consistently lower in plots with long-term ammonium fertilization. For all fertilized plots, soil pH was lowest at the depth of fertilizer placement (5-10 cm) and highest at 10-20 cm, with the greatest pH differences between these depths in no-till plots. Acidification altered exchangeable cation concentrations, decreasing exchangeable calcium and increasing exchangeable aluminum; this indicates that buffering capacity was reduced in many of the studied soils. These results show that acidification is a concern for neutral-pH Canadian soils, warranting further investigation.

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  • 10.1111/j.1475-2743.1986.tb00669.x
Soil acidification during more than 100 years under permanent grassland and woodland at Rothamsted
  • Mar 1, 1986
  • Soil Use and Management
  • A E Johnston + 2 more

Soil samples have been taken periodically from unlimed plots of the 130‐year‐old Park Grass Experiment and from the 100‐year‐old Geescroft Wilderness at Rothamsted. Changes in the pH of the samples show how acidification has progressed. The soils are now at, or are approaching, equilibrium pH values which depend on the acidifying inputs and on the buffering capacities of the soils. We have calculated the contributions to soil acidification of natural sources of acidity in the soil, atmospheric deposition, crop growth and nutrient removal, and, where applicable, additions of fertilizers. The relative importance of each source of acidification has changed as the soils have become more acid. Acid rain (wet deposited acidity) is a negligible source, but total atmospheric deposition may comprise up to 30% of acidifying inputs at near neutral soil pH values and more as soil pH decreases. Excepting fertilizers, the greatest causes of soil acidification at or near neutral pH values are the natural inputs of H + from the dissolution of CO 2 and subsequent dissociation of carbonic acid, and the mineralization of organic matter. Under grassland, single superphosphate and small amounts of sodium and magnesium sulphates have had no effect on soil pH, whilst potassium sulphate increased soil acidity slightly. All of these effects are greatly outweighed under grassland, however, by those of nitrogen fertilizers. Against a background of acidification from atmospheric, crop and natural inputs, nitrogen applied as ammonium sulphate decreased soil pH up to a maximum of 1.2 units at a rate in direct proportion to the amount added, and nitrogen applied as sodium nitrate increased soil pH by between 0.5 and 1 unit.

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  • Cite Count Icon 4
  • 10.1007/s11367-023-02199-1
Regionalized life cycle inventory data collection and calculation for perennial forage production in Canada: methodological best practices and limitations
  • Aug 7, 2023
  • The International Journal of Life Cycle Assessment
  • Sarah J Pogue + 11 more

PurposeIn Canada, 95–99% of produced forages are consumed domestically each year, mainly by beef cattle. Despite their importance, their contribution to the Canadian livestock industry and associated ecosystem services has not been investigated. This study developed a life cycle inventory (LCI) of perennial forage production in Canada averaged from 2009 to 2018.MethodsLCI data were sourced or calculated from up-to-date, regionally resolved sources and models. Inputs to perennial forage production included the following: concrete, steel, and plastic usage; machinery fuel consumption; electricity, natural gas, and water use for irrigation; and synthetic and organic fertilizer, lime, and herbicide use. Assessed emissions included ammonia and nitrous oxide (N2O); carbon dioxide from energy use; herbicide, nitrate, and phosphate losses; and soil carbon accumulation. Results were expressed per metric tonne of harvested perennial forage dry matter at provincial and regional scales—Western Canada [British Columbia (BC), Alberta (AB), Saskatchewan (SK), Manitoba (MB)] and Eastern Canada [Ontario (ON), Québec (QC)].Results and discussionRates of inputs varied, with generally lower nutrient but higher herbicide application in West vs. East. Irrigation was highest in BC, followed by AB and SK; energy consumption was highest in BC and lowest in QC. Higher N2O losses and nutrient losses via leaching and runoff in the East were partially due to greater soil moisture. Although total harvested perennial forage area declined from 6.43 to 5.23 million hectares from 2009 to 2018, these lands continued to accumulate soil carbon. The time period used to calculate average yields affected LCI estimates, as prairie yields were lower 1994–2003/1999–2008 due to drought. Furthermore, soil carbon sequestration estimates were affected by the annual change coefficients employed, underscoring the need for careful interpretation of LCI outputs. Results were compared to other studies and highlighted the importance of the choice of data and methods in creating LCI, and the need for transparency.ConclusionsThis first national LCI of perennial forage production in Canada provides a baseline for LCI inputs and outputs associated with this sector, highlighting provincial and regional differences. Outputs can be used to conduct future life cycle assessments to assess the environmental impacts of forage production and generate recommendations to improve sustainability, and for education and marketing purposes. This study demonstrates methodological best practices for LCI data mining and calculations, within available data and model limitations, thereby identifying gaps and providing a roadmap for other countries or sectors to develop detailed forage LCI.

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  • 10.1080/07060668609501813
Abstracts of papers presented at the annual meeting of the Canadian Phytopathological Society University of Saskatchewan, Saskatoon 27-30 July 1986
  • Sep 1, 1986
  • Canadian Journal of Plant Pathology

(1986). Abstracts of papers presented at the annual meeting of the Canadian Phytopathological Society University of Saskatchewan, Saskatoon 27-30 July 1986. Canadian Journal of Plant Pathology: Vol. 8, No. 3, pp. 347-357.

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The role of plant residues in pH change of acid soils differing in initial pH
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Can high overall human papillomavirus vaccination coverage hide sociodemographic inequalities? An ecological analysis in Canada
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Estimating temporal changes in soil pH in the black soil region of Northeast China using remote sensing
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Estimating temporal changes in soil pH in the black soil region of Northeast China using remote sensing

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  • Cite Count Icon 33
  • 10.2307/2403085
Primary Production of a Grassland in Nairobi National Park, Kenya
  • Apr 1, 1986
  • The Journal of Applied Ecology
  • I Deshmukh

Taking the solar greenhouses with different cultivating years and vegetables in Ji'nan as test objects, this paper studied the amounts and frequency distribution of soil nutrients and the relationships between cultivating years and soil nutrients accumulation characteristics, and analyzed the factors causing soil salinization and acidification by fitting soil nutrients contents with cultivating years and vegetables. In the greenhouses, the contents of soil alkali-hydrolysable nitrogen, available phosphorus, available potassium, organic matter, and electrical conductivity were significantly higher than those in the open field, with an increment of 135.3%, 475.2%, 290.1%, 97.7%, and 188.7%, respectively, but the soil pH value was 0.31 lower than that of open field. The frequency distribution of soil nutrients presented a normal curve. Differences were observed in the soil nutrients contents in the greenhouses with different cultivating vegetables. The soil alkali-hydrolysable nitrogen content and electrical conductivity were in the order of tomato > cucumber > sweet pepper, soil organic matter content and pH value were cucumber > sweet pepper > tomato, soil available phosphorus content was cucumber > tomato > sweet pepper, and soil available potassium content was tomato > cucumber > sweet pepper. There was a mild tendency of soil acidification in soil alkali-hydrolysable nitrogen and available potassium. The decrease of soil pH was closely related to the accumulation of alkali-hydrolysable nitrogen. The soil nutrients accumulation in the greenhouses had the similar patterns, i. e. , rapid accumulation in the first two cultivating years, slowed down in the third and fourth year, and kept stable later, demonstrating a dynamic balance on the whole. All the nutrients contents were positively accumulated, while soil pH presented negatively. In the greenhouses with different cultivating vegetables, there was a significant correlation between soil nutrients and cultivating years, which could be fitted by conic curve or cubic curve.

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Continuous plastic-film mulching increases soil aggregation but decreases soil pH in semiarid areas of China
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  • Lin Wang + 7 more

Continuous plastic-film mulching increases soil aggregation but decreases soil pH in semiarid areas of China

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  • 10.1080/15324989309381352
Sodic soil reclamation with saline water in conjunction with organic and inorganic amendments
  • Jul 1, 1993
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  • S K Dubey + 1 more

A greenhouse experiment was conducted to evaluate the effect of soil amendments on the growth, yield, and mineral composition of rice and wheat grown in a highly sodic soil (pH 10.6, exchangeable Na+ 95%). The soil amendments were gypsum at 50% gypsum requirement (GR), pyrite 50% GR on equivalent sulfur basis, farmyard manure (FYM) 1%, gypsum 50% GR + FYM1%, pyrite 50% GR + FYM 1%, and control (no amendment). Saline (EC 4 dS m‐1) and nonsaline (EC 0.4 dS m‐1) water was used for irrigation. Irrespective of the amendments used, soil pH and exchangeable sodium percentage (ESP) decreased due to an initial 10 days submergence, and more with saline water. Application of amendments significantly enhanced the yield of both crops and decreased ESP, irrespective of the quality of irrigation water used and followed the order gypsum + FYM > pyrite + FYM > gypsum > pyrite > FYM > control. The magnitude of increase in the yield of wheat was higher as compared to rice following amendments application. Use of saline water resulted in significantly higher yield of both crops. Decrease in soil pH and ESP was greater after rice than wheat, particularly when nonsaline water was used. However, irrigation of wheat with saline water further decreased the soil pH and ESP.

  • Book Chapter
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  • 10.1016/s1572-4409(99)80162-x
Reduction of soil pH using Thiobacillus cultures
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  • Process Metallurgy
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  • Cite Count Icon 7
  • 10.3390/microorganisms12050949
Green Manuring Enhances Soil Multifunctionality in Tobacco Field in Southwest China.
  • May 7, 2024
  • Microorganisms
  • Yu Feng + 6 more

The use of green manure can substantially increase the microbial diversity and multifunctionality of soil. Green manuring practices are becoming popular for tobacco production in China. However, the influence of different green manures in tobacco fields has not yet been clarified. Here, smooth vetch (SV), hairy vetch (HV), broad bean (BB), common vetch (CV), rapeseed (RS), and radish (RD) were selected as green manures to investigate their impact on soil multifunctionality and evaluate their effects on enhancing soil quality for tobacco cultivation in southwest China. The biomass of tobacco was highest in the SV treatment. Soil pH declined, and soil organic matter (SOM), total nitrogen (TN), and dissolved organic carbon (DOC) content in CV and BB and activity of extracellular enzymes in SV and CV treatments were higher than those in other treatments. Fungal diversity declined in SV and CV but did not affect soil multifunctionality, indicating that bacterial communities contributed more to soil multifunctionality than fungal communities. The abundance of Firmicutes, Rhizobiales, and Micrococcales in SV and CV treatments increased and was negatively correlated with soil pH but positively correlated with soil multifunctionality, suggesting that the decrease in soil pH contributed to increases in the abundance of functional bacteria. In the bacteria-fungi co-occurrence network, the relative abundance of key ecological modules negatively correlated with soil multifunctionality and was low in SV, CV, BB, and RS treatments, and this was associated with reductions in soil pH and increases in the content of SOM and nitrate nitrogen (NO3--N). Overall, we found that SV and CV are more beneficial for soil multifunctionality, and this was driven by the decrease in soil pH and the increase in SOM, TN, NO3--N, and C- and N-cycling functional bacteria.

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  • Cite Count Icon 9
  • 10.1656/045.018.0204
Diminished Soil Quality in an Old-Growth, Mixed Mesophytic Forest Following Chronic Acid Deposition
  • May 1, 2011
  • Northeastern Naturalist
  • Jared L Deforest + 1 more

Human activities have increased acid deposition throughout the Ohio River Valley due to the large number of coal-fired power-generating facilities. The long-term effects of chronic acid deposition can include a decrease in soil pH, loss of soil fertility, and a decrease in base saturation—all of which can reduce forest productivity. Dysart Woods, a remnant old-growth, mixed mesophytic forest in eastern Ohio, has experienced a decrease in soil pH from 5.0 in 1971 to 4.6 in 1997, which may be due to chronic acid deposition. The objective of this study was to utilize a long-term study to evaluate how soil quality has changed due to chronic acid deposition. To meet the study objectives, a variety of soil chemical properties (pH, base saturation, C, N, P, etc.) were measured from surface soil within two stands of opposing aspect at Dysart Woods within the unglaciated Allegheny Plateau. Because soil pH correlates strongly with other soil chemical properties, we used pH data from 1971 to estimate how soil quality has changed over time. Mean soil pH from the south-facing stand was 5.0 in 1971, 4.6 in 1997, and 4.3 in 2007. While soil pH was not measured in the north-facing stand in 1971, pH was 4.6 in 1997 and 4.7 in 2007. Using changes in pH to estimate past soil properties, our results suggest that available base cations in the south-facing stand have been reduced from ≈12 to 6 (cmolc kg-1), with a 50% reduction in base saturation since 1971. Considering that both stands receive the same amount of acid deposition due to their close proximity to each other, results raise an interesting question: Are unglaciated Allegheny Plateau south-facing soils more susceptible to the effects of acid deposition than north-facing soils?

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  • Cite Count Icon 32
  • 10.3389/fsufs.2022.821397
Effect of Biochar on Micronutrient Availability and Uptake Into Leafy Greens in Two Urban Tropical Soils With Contrasting Soil pH
  • May 10, 2022
  • Frontiers in Sustainable Food Systems
  • Alfonso Rodríguez-Vila + 8 more

Biochars have been proposed as a novel biotechnology to increase crop yields in acidic soils due to a liming effect. However, the application of biochar to soils with a neutral soil pH is less likely to improve yield. A rise in pH typically increases the availability of macronutrients (e.g., PO43-, NO3-) but biochar is known to immobilize some elements due to a pH increase and adsorption on the biochar surface. Therefore, biochar application may reduce the uptake of important micronutrients (e.g., Cu, Fe, and Zn) into the edible portions of food crops. Before recommending indiscriminate biochar application to tropical soils, an understanding of the potentially negative impacts of biochar application to contrasting soil types should be fully appreciated to prevent unintended consequences. Our aim was to determine the impact of biochar amendment to an acidic soil and a neutral soil on micronutrient availability and uptake into leafy greens. We produced biochars from 3 different organic feedstock materials (corn cobs, rice husk and teak sawdust) and applied these in pot experiments to an acidic tropical soil (pH 4.5) and a neutral tropical soil (pH 6.9) collected from urban farms in Tamale and Kumasi, respectively, in Ghana. We grew leafy greens (Amaranthus, Corchorus, and Lettuce) and measured their growth and the uptake of Cu, Fe, and Zn, alongside supporting measurements of soil pH and micronutrient availability in the soil. We also measured water soluble Cu, Fe, and Zn in the soils amended with biochars pyrolyzed at different temperatures. The corn cobs biochar increased soil pH and considerably increased plant growth in the acidic soil from Tamale. In the neutral soil from Kumasi we found that, while corn cob biochar increased soil pH, rice husk biochar decreased soil pH. Furthermore, corn cob biochar considerably reduced plant growth in the neutral soil. The concentration of micronutrients in the edible portions of leafy greens was not greatly affected by biochar application, but the total uptake (i.e., concentration multiplied by biomass) of micronutrients into leaves was generally increased by biochar application in the acidic (Tamale) soil and application of the corn cob biochar generally decreased total uptake of micronutrients in the neutral (Kumasi) soil. Our results highlight the need for site-specific information on biochar feedstock and soil pH prior to recommending biochar application to tropical urban soils so that the benefits can be optimized and unintended consequences can be prevented.

  • Research Article
  • Cite Count Icon 76
  • 10.1023/b:plso.0000030173.71500.e1
Zinc mobilisation from a contaminated soil by three genotypes of tobacco as affected by soil and rhizosphere pH
  • Mar 1, 2004
  • Plant and Soil
  • ¡Aff1¿Nancy Loosemore + 3 more

The aim of this research was to evaluate the effect of soil and rhizosphere pH on the mobilisation of Zn by various tobacco genotypes. One-month-old tobacco plants were grown for 8 days on top of a thin layer of an arable soil that had been sampled near a Zn smelter. A range of rhizosphere pH values was obtained either by growing nitrate-fed tobacco on top of the soil amended with various amounts of acid or lime, or by growing tobacco on top of the unamended soil with nitrate or ammonium supply. In the latter case, we used three genotypes that were assumed to differ in their ability to accumulate Zn or acidify the rhizosphere and, hence, mobilise soil Zn. In spite of the moderate level of contamination of the soil, tobacco took up substantial amounts of soil Zn. No difference was found between the three genotypes. Exchangeable Zn steeply increased with decreasing soil pH, which could be adequately modelled with a simple model. Whatever the source of nitrogen supplied, a significant acidification occurred in the rhizosphere. This explains why the observed Zn mobilisation was larger than expected on the basis of bulk soil pH values. Taking account of the change of pH induced by tobacco roots is thus of prime importance for better predicting the actual amount of exchangeable Zn in the rhizosphere and, thereafter the bioavailability of soil Zn.

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