Ammonia recovery from anaerobic digestion effluent by aeration-assisted membrane contactor

Abstract

The ammonia recovery from anaerobic digestion (AD) effluent offers a low cost and low carbon footprint strategy for N recovery. To enhance ammonia recovery performance, the aeration-assisted membrane contactor (MC) process was presented with aeration applied on the feed side. The ammonia recovery performance with different pH adjustment methods and operating parameters were tested. Results illustrated that a high ammonia mass transfer coefficient (Kov = 4.85 ×10−7 m/s) could be achieved in the aeration-assisted MC. With the increase in air flow rate from 0 L/min to 0.6 L/min, the Kov increased from 1.21 × 10−7 m/s to 4.85 × 10−7 m/s by about 300%, and the ammonia separation factor (St) increased from 5.75 to 8.91 by about 55%. Additionally, the Kov increased sharply with the increase in feed temperature. Notably, the ammonia removal efficiency can reach 82% after 6-h experiment, which might be due to the large contact area of membrane contactor and the high mass transfer efficiency caused by the optimal conditions. The greenhouse gas (GHG) emission evaluation showed that compared with that of Haber-Bosch process (4.2 kg-CO2 eq/kg-N), the GHG emission of aeration-assisted MC was 1.86 kg-CO2 eq/kg-N under room temperature. The aeration-assisted MC can provide a high-efficient and low GHG-emission ammonia recovery process.