Abstract

Abstract While investigating the reaction mechanism in the triple system N+H4X−+CH2O+H3PP3, much attention was paid to determining the stages of the interaction which can be presented as follows: The mechanism of the stage (2) and the possible alternative processes have not been sufficiently developed. If phosphite-anion is present in the system, one might assume that hydrogen attached to phosphorus can be involved in the hydride transfer reactions: Indeed, the reactions of ammonium salts of phosphorous acid with aldehydes in aqueous media result in ammonium salts of phosphoric acid, i.e. the reduction of the intermediately formed a-oxymethylamine to tertamine occurs and the oxidation of phosphite-anion to phosphate-anion takes place.

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