Alkaline hydrothermal zeolites synthesized from high SiO 2 and Al 2O 3 co-disposal fly ash filtrates

Abstract

A co-disposal reaction was used wherein fly ash (FA) was reacted with acid mine drainage (AMD), to collect filtrates for zeolite synthesis. Raw fly ash as well as fly ash leached with HCl were subjected to the same alkaline hydrothermal zeolite synthesis conditions, as for the co-disposal filtrates, in order to evaluate the zeolitic material obtained. The Si and Al contents of the fly ash (FA) filtrates were used as precursor species for the alkaline hydrothermal conversion of the fly ash filtrates into zeolites. These filtrates were then analysed by XRF spectrometry for quantitative determination of SiO 2 and Al 2O 3. The [SiO 2]/[Al 2O 3] ratio obtained in the filtrates range from 1.4 to 2.5. The [SiO 2]/[Al 2O 3] ratio was used to predict whether the fly ash filtrates could successfully be converted into faujasite zeolitic material by the adopted synthesis procedures. If the [SiO 2]/[Al 2O 3] ratio is higher than 1.5 in the co-disposal filtrates, it favours the formation of faujasite. The zeolite synthesis included an alkaline fusion of the co-disposal filtrates, followed by aging for 8 hours and hydrothermal conversion by crystallisation at 100 °C. Different variables were investigated during the synthesis of zeolite to ascertain their influence on the end product. These variables include adding different amounts of deionised water to the FA-related starting material, using different compositions of FA related starting material and different FA:NaOH ratios in fusing the starting material.