Abstract
Single-walled carbon nanotubes (SWNTs) were chemically functionalized with amphiphilic octadecylamine after purification. Lower density and highly oriented SWNTs were obtained via Langmuir–Blodgett (LB) technique. A model was introduced to explain the compression-induced alignment. The phase behavior of the spreading monolayer was studied by surface pressure-area isotherms at different temperatures and different compression speeds. The transferred LB films of SWNTs with different mean lengths were investigated by the field emission scanning electron microscopy, showing that SWNTs with average length at 1000–2000 nm have more preference of reorientation upon compression than shorter ones (∼500 nm), while SWNTs that are too long (∼3000 nm) would tangle together and the reorientation is weaker. Multilayers (up to 18 layers) of SWNTs were obtained with high transfer ratios (>0.93) and the UV-vis absorption spectra indicated that the layer-by-layer deposition was successful.
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