Abstract
We observe the influence of Al occupancies in Li sites on the formation process of the garnet solid electrolyte of Li7La3Zr2O12 (LLZO). A direct incorporation of Al is first promoted in a Li-insufficient garnet solid electrolyte during the calcination process of 850 °C and then the cubic phase of LLZO is obtained after successive annealing step of 1000 °C. Comparing to pristine LLZO, Al incorporated LLZO shows less formation of Li2CO3, keeping crystallographic and physicochemical properties. This Al incorporation improves both the ionic conductivity and interfacial resistance to poisoning procedure.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
