Agreements and disagreements between theories and experiments in nematoviscosity.

Abstract

In this work a set of viscosity data selected from the nematic liquid crystals literature is compared with the currently accepted microscopic (molecular) theories for the nematic viscosity. It is shown that the kinetic theory of Doi [N. Kuzuu and M. Doi, J. Phys. Soc. of Jpn. 52, 3486 (1983)] and the affine transformation theory of Hess [D. Baalss and S. Hess, Phys. Rev. Lett. 57, 86 (1986)] equally predict that Miesowicz's coefficients of a given sample are not independent but, as it has been believed for many years [H. Kneppe, F. Scheneider, and N. K. Sharma, Ber. Bunsenges Phys. Chem. 85, 784 (1981)], they are connected by a linear relationship. Such conjecture gains a strong positive support when it is applied to a set of experimental data that we have collected. However, when these data are used to obtain the values of the parameters used to build these theories, it is found that the values assumed by them are in flagrant disagreement with the physical interpretation that they are supposed to have.