Abstract
Metal complexes of alkynyl carbenes undergo a [1,3]-bond shift known as a metallotropic shift. Since the discovery of the metallotropic [1,3]-shift of Rh-carbenoid, many more alkynyl carbene complexes with Ti, Cr, Mn, Mo, Ru, W, Re, Pt, and Au have been discovered to show metallotropic shift behavior. This article briefly summarizes the [1,3]-bond shift of alkynyl carbenes and their metal complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
