Abstract
Following an introduction into solvent radical-cage effects and the general use of cage-trapping methods to study solvent-cage effects, the bio-organometallic enzyme cofactor coenzyme B 12 (adocobalamin; AdoCbl) in studied using the TEMPO (2,2,6,6-tetramethylpiperidinyl-1-oxy) nitroxide cage-trapping method. Specifically, the products, kinetics, and mechanism of AdoCbl Co-C thermolynin in ethylene glycol are presented at high [TEMPO], results which establish (after ruling out other conceivable mechanisms and interpretations) a radical-cage effect for AdoCbl in ethylene glycol
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