Abstract
The Bu 3SnH - AIBN induced radical additions of 5- 0 -benzoyl-2,3- 0 -isopropylidene-1- 0 -methylthiothiocarbonyl-β-D-ribofuranose ( 1) to olefins such as dimethyl maleate, methyl vinyl ketone, methyl acrylate etc. gave corresponding C-ribofuranosyl compounds. And one of the adducts was converted to the key intermediate of a showdomycin synthesis.
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