Abstract

AbstractThree isomeric aminopyridines were reacted with an excess of benzoyl chloride in the presence of an excess of triethylamine, giving the corresponding dibenzoylaminopyridines in high yields. As an application of the dibenzoylation, the aminopyridines were also reacted with phthaloyl dichloride, resulting in appreciable yields of the respective N‐pyridylphthalimides. The rate of the conversion under various conditions was studied with high pressure liquid chromatography in order to investigate the difference in reactivity among the three isomers.

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