Abstract
The action of Me 2NHAlCl 3 on acylferrocenes is a convenient route to ferrocenylimmonium ions FcC(R) N + Me 2. Derivatives with R = H(I), Ph(II), 2-(CH 3) 2 (III) have been prepared. We examined some properties of the salts: NMR, action of diazomethane and reduction with potassium borohydride. This reduction is illustrated by the synthesis of the endo amine (IV). ▪
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