Abstract

An acoustic resonant spectroscopy technique for measuring the acoustic impedance, ultrasonic velocity, and density of micron-scale polymer films is developed. The method, which is based on spectral analysis, observes the acoustic resonance between water, the film, and a tungsten plate with high acoustic impedance in the frequency range of 20–70MHz. The interface between the film being examined and the plate is vacuum sealed, enabling us to characterize the low-density polyethylene film with acoustic impedances as low as about 1.9MNm−3s and the poly(vinyl chloride) film as thin as about 8μm. The error in the film density measurements is found to be less than 1%, and the validity of the technique is verified.

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