Achievements of the RIANA and AWACSS EU Projects: Immunosensors for the Determination of Pesticides, Endocrine Disrupting Chemicals and Pharmaceuticals

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This work was funded by the “Automated Water Analyser Computer Supported System” (AWACSS) (EVK1-CT-2000-00045) research project supported by the European Commission under the Fifth Framework Programme and contributing to the implementation of the Key Action “Sustainable Management and Quality of Water” within Energy, Environment and Sustainable Development. This work reflects only the authors’ views and the EU is not liable for any use that may be made of the information contained therein.

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Amperometric Biosensor for Continuous Monitoring Irgarol 1051 in Sea Water
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Abstract Irgarol 1051 is one of the most employed antifouling agents and is one of the most commonly found in marine environment. According to its widespread use the European Comission turned its attention on this agent as one of the priority substances that has to be controlled. The aim of this article is to develop an immunosensor for the determination of Irgarol 1051 in sea water for implementation in a flow analysis system. The transducing principle employed for its development was an amperometric detection using gold screen printed electrodes which were functionalized for the covalent immobilization of the immunoreagents. The detection of Irgarol 1051 was performed using specific antibodies working under competitive indirect format. The immunosensor was demonstrated to measure directly in sea water with high detectability, accurately and robust. The system allows consecutive measurements using the same chip owing to an easy regeneration process. The limit of detection reached was 0.15±0.09 nM (0.038±0.022 µg ⋅ L−1) measured directly in sea water.

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Emerging Organic Contaminants and Nanomaterials in Food
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Abstract Governments all over the world are intensifying their efforts to improve food safety. These efforts come as a response to an increasing number of food safety problems and rising consumer concerns. In addition, the variety of toxicant residues in food is continuously increasing as a consequence of industry development, new agricultural practices, environmental pollution, and climate change. This paper reviews the major groups of emerging contaminants in food, as well as, the levels of concentrations reported and the analytical approaches presented for their detection with special emphasis on more fast and cost-efficient methods of detection.The four main groups of emerging food contaminants that are discussed here are: 1. Industrial organic pollutants: Perfluorinated compounds (PFCs), polybrominated diphenylethers (PBDEs), new pesticides, and nanomaterials. 2. Pharmaceutical residues: Antibiotics and coccidiostats 3. Biotoxins: Emerging groups of marine biotoxins KeywordsBiotoxinsCoccidiostatsFood contaminantsLC-MS/MSNanomaterials antibioticsPerfluorinated compoundsPesticidesPolybrominated diphenylethers

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Automatic High Frequency Monitoring for Improved Lake and Reservoir Management.
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Recent technological developments have increased the number of variables being monitored in lakes and reservoirs using automatic high frequency monitoring (AHFM). However, design of AHFM systems and posterior data handling and interpretation are currently being developed on a site-by-site and issue-by-issue basis with minimal standardization of protocols or knowledge sharing. As a result, many deployments become short-lived or underutilized, and many new scientific developments that are potentially useful for water management and environmental legislation remain underexplored. This Critical Review bridges scientific uses of AHFM with their applications by providing an overview of the current AHFM capabilities, together with examples of successful applications. We review the use of AHFM for maximizing the provision of ecosystem services supplied by lakes and reservoirs (consumptive and non consumptive uses, food production, and recreation), and for reporting lake status in the EU Water Framework Directive. We also highlight critical issues to enhance the application of AHFM, and suggest the establishment of appropriate networks to facilitate knowledge sharing and technological transfer between potential users. Finally, we give advice on how modern sensor technology can successfully be applied on a larger scale to the management of lakes and reservoirs and maximize the ecosystem services they provide.

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Abstract In recent years, the diverse industrial practices and human inputs widely disseminated emerging contaminants (ECs) throughout environmental matrices, which is of great concern. Even at low concentrations, ECs pose major ecological problems and threaten human health and the environment’s biota. Consequently, people’s interest and concerns on the widespread dissemination of environmentally connected ECs of great concern as developed due to their scientific understanding, technical innovation, and socioeconomic awareness. Increased detection of contaminants may occur from climatic, socioeconomic, and demographic changes and the growing sensitivity of analytical techniques. Hence, this article reviews the determination of ECs in ecological specimens, from aquatic setup (river water, marine water, and wastewater), sludge, soil, sediment, and air. Sample collection and the quality measures are summarized. The preparation of samples, including extraction and cleanup and the subsequent instrumental analysis of ECs, are all covered. Traditional and recent extraction and cleanup applications to analyze ECs in samples are reviewed here in this paper. The detection and quantification of ECs using gas chromatography (GC) and liquid chromatography (LC) linked with various detectors, particularly mass spectrometry (MS), is also summarized and explored, as are other possible techniques. This study aims to give readers a more excellent knowledge of how new and improved approaches are being developed and serve as a resource for researchers looking for the best method for detecting ECs in their studies.

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  • Agriculture
  • Anatolii Kucher + 5 more

Management based on sustainable approaches increases the resilience of systems in which they are implemented. The following study explores the sustainability and efficiency of water management in the regions of Ukraine and the role of these factors in its resilient development. The study conducts a bibliometric analysis of sources on sustainable water management, a comprehensive assessment of water resource efficiency in the regions of Ukraine, identifies and maps regional differences, and analyzes their dynamics over the period 2016–2020. The assessment shows that almost half of the regions (48.3%) have sufficient water management efficiency, 40.8% are very high, and 10.9% are average. Most regions (79.2%) maintained the same level of water resource efficiency. The Kharkiv region was examined in-depth, revealing higher water losses during transport and municipal/household sectors than the national average. Based on the assessment’s results, a differentiated approach to sustainable water management should be taken, depending on the type of regions. For regions with a very high and sufficient level of water efficiency, strategies to maintain the achieved positions should be implemented, while for regions with an average level of efficiency, strategies to improve the respective indices should be implemented. These research findings and policy recommendations can be utilized to guide policy-makers aiming to enhance the economic mechanism of sustainable water management at regional and national levels and improve their resilience to face the intensifying challenges.

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