Abstract

The experimental determination of Avogadro's number by the x-ray-density method is uncertain because of imperfections in crystals. It is proposed to regard the lattice of purest calcite as a reference lattice because of its proximity to a sound lattice, and to accept the value ${N}_{0}=6.02567\ifmmode\times\else\texttimes\fi{}{10}^{23}$ g ${\mathrm{mole}}^{\ensuremath{-}1}$ (phys.) which is equivalent to 6.02403\ifmmode\times\else\texttimes\fi{}${10}^{23}$ g ${\mathrm{mole}}^{\ensuremath{-}1}$ (chem.) for Avogadro's number as derived from measurements on pure calcite. The perfection of the lattices of all other crystalline substances then would be determined in comparison with the calcite as either sound (equal in perfection to that of calcite) within the error limits or as defective (vacancies, interstitial atoms), using the number above for the calculations.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.