Abstract
On the basis of rod-shaped secondary building units (SBUs), a novel two-dimensional (2D) azide–copper polymer, [Cu3(N3)4(anol)2]∞ (1; anol=aminoethanol), was synthesized and structurally characterized. Complex 1 is a neutral 2D coordination network consisting of trinuclear copper(II) clusters [Cu3(N3)4(anol)2] connected with the bridge of end-end (EE) azide group. Magnetic data analysis shows that a metamagnetic behavior is observed for 1 which is associated with significant ferromagnetic coupling intracluster over 4K.
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