Abstract
The radiation-chemical decomposition of n-hexane in the Al-n-hexane system under the action of gamma radiation was studied by reflectance-absorption IR spectroscopy. The radiolysis of n-hexane on the surface of aluminum at absorbed doses of 5 kGy ≤ D γ ≤ 40 kGy was accompanied by the formation of aluminum alkyls, π-complexes of olefins, and aluminum hydrides. The kinetics of the accumulation of molecular hydrogen was analyzed to determine its radiation-chemical yield, G ads (H2) = 29.6 molecules/100 eV. A possible mechanism of this process is discussed.
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