Abstract

The study of thermal desorption of hydrogen from amorphous Ni 64Zr 36 alloys provided evidence for a distribution of hydrogen among sites of different energy caused by the disorder in an amorphous metal. The amorphous Ni 64Zr 36 alloy has at least two kinds of hydrogen occupation sites of different chemical environment. This was confirmed by hydrogen thermal desorption techniques which indicate that the dissolotion of hydrogen is exothermic. Pressure-concentration isotherms show positive deviations from Sievert's law at temperatures of 423 K and 523 K for hydrogen pressures up to 1 atm. This is related to the distribution of hydrogen atoms in sites of different energies.

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