Abstract
Due to the simultaneously unknown individual ion activity coefficients and liquid-junction potentials, a reasonable convention must be introduced defining the former in order to permit the calculation of the latter. The Guggenheim convention is analysed and chosen.Examples are reported of determination of potentials arising at junctions between concentrated strong acids and salt bridges. Liquid junction potentials set up between two concentrated strong acids at identical molalities are also considered, on the basis of a modified Henderson equation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
