Abstract
Abstract Several 2-(arylazo)-N-alkyl aniline ligands, 1a–11a, have been prepared by the reaction between 2-(arylazo) aniline and the appropriate alkyl halide in the presence of K2CO3. Treatment of sodium tetrachloropalladate with 1a–11a in methanol afforded the orthopalladated complexes 1b–11b, where the ligand is tridentate (C,N,N). The ligands and complexes were characterised from spectroscopic data and confirmed by X-ray studies. The X-ray structure of 9b displayed an unsupported Pd(II)⋯Pd(II) interaction (3.301 A).
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